Keywords

Anomeric effectChemistryAntibonding molecular orbitalAnomerMolecular orbitalMoleculeCrystallographyAb initioAlkane stereochemistryComputational chemistryLone pairAtomic orbitalStereochemistryPhysicsOrganic chemistryElectronQuantum mechanics

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Correlation of the hydrogen-bond acceptor properties of nitrogen with the geometry of the N<i>sp</i> <sup> <i>2</i> </sup>→N<i>sp</i> <sup> <i>3</i> </sup> transition in <i>R</i> <sub>1</sub>(<i>X</i>=)C–N<i>R</i> <sub>2</sub> <i>R</i> <sub>3</sub> substructures: reaction pathway for the protonation of nitrogen

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Publication Info

Year
1979
Type
article
Volume
69
Issue
1
Pages
1-26
Citations
169
Access
Closed

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Saul Wolfe, Myung‐Hwan Whangbo, David J. Mitchell (1979). On the magnitudes and origins of the “anomeric effects”, “exo-anomeric effects”, “reverse anomeric effects”, and CX and CY bond -lengths in XCH2YH molecules. Carbohydrate Research , 69 (1) , 1-26. https://doi.org/10.1016/s0008-6215(00)85747-x

Identifiers

DOI
10.1016/s0008-6215(00)85747-x