Saul Wolfe

Gauche effect. Stereochemical consequences of adjacent electron pairs and polar bonds

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTGauche effect. Stereochemical consequences of adjacent electron pairs and polar bondsSaul WolfeCite this: Acc. Chem. Res. 1972, 5, 3,...

On the magnitudes and origins of the “anomeric effects”, “exo-anomeric effects”, “reverse anomeric effects”, and CX and CY bond -lengths in XCH2YH molecules

Theoretical studies of SN2 transition states. 2. Intrinsic barriers, rate-equilibrium relationships, and the Marcus equation

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTheoretical studies of SN2 transition states. 2. Intrinsic barriers, rate-equilibrium relationships, and the Marcus equationSaul Wolf...

<i>A</i> <i>b</i> <i>i</i> <i>n</i> <i>i</i> <i>t</i> <i>i</i> <i>o</i> computation of force constants. The second and third period hydrides

The force method has been employed to calculate the force constants of HF, H2O, NH3, CH4, HCl, H2S, PH3, and SiH4. The computations were performed using wavefunctions generated ...