Abstract

A method combining laser ablation cluster formation and vapor-liquid-solid (VLS) growth was developed for the synthesis of semiconductor nanowires. In this process, laser ablation was used to prepare nanometer-diameter catalyst clusters that define the size of wires produced by VLS growth. This approach was used to prepare bulk quantities of uniform single-crystal silicon and germanium nanowires with diameters of 6 to 20 and 3 to 9 nanometers, respectively, and lengths ranging from 1 to 30 micrometers. Studies carried out with different conditions and catalyst materials confirmed the central details of the growth mechanism and suggest that well-established phase diagrams can be used to predict rationally catalyst materials and growth conditions for the preparation of nanowires.

Keywords

NanowireMaterials scienceNanometreLaser ablationSemiconductorVapor–liquid–solid methodNanotechnologyGermaniumLaserSiliconCrystal growthLaser ablation synthesis in solutionCatalysisCrystal (programming language)OptoelectronicsOpticsLaser power scalingCrystallographyChemistryComposite materialX-ray laser

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Publication Info

Year
1998
Type
article
Volume
279
Issue
5348
Pages
208-211
Citations
4347
Access
Closed

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Alfredo Morales, Charles M. Lieber (1998). A Laser Ablation Method for the Synthesis of Crystalline Semiconductor Nanowires. Science , 279 (5348) , 208-211. https://doi.org/10.1126/science.279.5348.208

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DOI
10.1126/science.279.5348.208