Transition Metal Squarates I. Chain Structures M (C4O4) · 4 H2O

Abstract

The transition metal squarates M(C 4 O 4 ) · 4 H 2 O (M 2+ = Mn 2+ , Fe 2+ , Co 2+ . Ni 2+ , and Zn 2+ ) are isotypic. They crystallize monoclinically, space group Ce-Cf, and consist of one-dimensional chain molecules [xxx] with the chain axes alternatively in direction [110] and [110]. The transition metal is octahedrally coordinated by two oxygen atoms of two C 4 O 4 2- -anions in rrarcs-position and 4 water molecules. Neighbouring chains are interlinked by hydrogen bonds. The distance between the planes of the parallel C 4 -rings of neighbouring chains is similar to the layer distance in graphite.

Keywords

CrystallographyTransition metalMoleculeChemistryChain (unit)GraphiteMetalHydrogen bondStereochemistryMaterials sciencePhysicsCatalysisOrganic chemistry

Affiliated Institutions

Ludwig-Maximilians-Universität München DE

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Publication Info

Year: 1986
Type: article
Volume: 41
Issue: 1
Pages: 18-24
Citations: 59
Access: Closed

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APA Style

                            
                                
                                    A. Weiss, 
                                
                                    Eugen Riegler, 
                                
                                    I. Alt
                                
                                et al.
                            
                            (1986). 
                            Transition Metal Squarates I. Chain Structures M (C<sub>4</sub>O<sub>4</sub>) · 4 H<sub>2</sub>O. 
                            Zeitschrift für Naturforschung B
                            , 41
                            (1)
                            , 18-24.
                            https://doi.org/10.1515/znb-1986-0105
                        

Identifiers

DOI: 10.1515/znb-1986-0105