Hybrid open frameworks (MIL-n). Part 6 Hydrothermal synthesis and X-ray powder ab initio structure determination of MIL-11, a series of lanthanide organodiphosphonates with three-dimensional networks, LnIIIH[O3P(CH2)nPO3] (n=1-3)
A series of lanthanide and yttrium propylenediphosphonates has been prepared hydrothermally (210°C, 4 days) by action of propylenediphosphonic acid on the metal chlorides. The c...