Abstract
The equilibrium configurations of a liquid spreading on a rough solid surface are derived by making expansions in terms of the characteristic slope ε of the surface roughness, which is assumed to be very small. It is also assumed that the microscopic contact angle is a constant and that the liquid–air interface is planar at large distances from the contact line. Expressions for the value of the macroscopic contact angle and a discussion of the existence of contact-angle hysteresis and of stick-jump behaviour of the contact line are given for (i) surfaces with parallel grooves, (ii) surfaces with periodicity in two perpendicular directions and (iii) general non-period surfaces.
Keywords
Affiliated Institutions
Related Publications
UPPER LIMITS FOR THE CONTACT ANGLES OF LIQUIDS ON SOLIDS
Abstract : Earlier systematic studies of the angle of contact (theta) exhibited by drops of liquid on plane solid surfaces of low surface energy have made data available on equi...
Contact Angle Hysteresis
An experimental study of the wettability of rough surfaces over an extremely wide range of roughness is described. The theoretical wettability behavior of an idealized, rough su...
Estimation of the surface free energy of polymers
Abstract A method for measuring the surface energy of solids and for resolving the surface energy into contributions from dispersion and dipole‐hydrogen bonding forces has been ...
Physical chemistry of surfaces
Capillarity. The Nature and Thermodynamics of Liquid Interfaces. Surface Films on Liquid Substrates. Electrical Aspects of Surface Chemistry. Long--Range Forces. Surfaces of Sol...
Contact Mechanics
This treatise is concerned with the stresses and deformation of solid bodies in contact with each other, along curved surfaces which touch initially at a point or along a line. ...
Publication Info
- Year
- 1983
- Type
- article
- Volume
- 131
- Pages
- 1-26
- Citations
- 105
- Access
- Closed
External Links
Social Impact
Social media, news, blog, policy document mentions
Citation Metrics
Cite This
Identifiers
- DOI
- 10.1017/s0022112083001214