Abstract

Abstract A method for measuring the surface energy of solids and for resolving the surface energy into contributions from dispersion and dipole‐hydrogen bonding forces has been developed. It is based on the measurement of contact angles with water and methylene iodide. Good agreement has been obtained with the more laborious γ c method. Evidence for a finite value of liquid‐solid interfacial tension at zero contact angle is presented. The method is especially applicable to the surface characterization of polymers.

Keywords

Contact angleSurface energySurface tensionPolymerMaterials scienceLondon dispersion forceDispersion (optics)Surface (topology)Free surfaceEnergy (signal processing)MethyleneIodideDipoleInverse gas chromatographyComposite materialThermodynamicsOpticsChemistryMoleculeOrganic chemistryPhysicsGeometry

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Publication Info

Year
1969
Type
article
Volume
13
Issue
8
Pages
1741-1747
Citations
8888
Access
Closed

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8888
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169
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Cite This

D.K. Owens, R. C. Wendt (1969). Estimation of the surface free energy of polymers. Journal of Applied Polymer Science , 13 (8) , 1741-1747. https://doi.org/10.1002/app.1969.070130815

Identifiers

DOI
10.1002/app.1969.070130815

Data Quality

Data completeness: 77%