Abstract
GdCI s. 6 He() is monoclinic with space group P2/n anti two molecules in the cell a=9"651, b=6-525, c=7.923A; fl=93"65 °.All atomic positions (except for hydrogen) were determined with high precision.The structure contains complexes Cl.~(Id(()H.,)6] which are heht togother by ()--H • • • C1 bonds.Thus one third of the chlorine atoms are not bonded to gadolinium atoms.The only symmetry element of a complex is a twofoht axis.The bond lengths are:(l(t-Ci =2.768, Gd-O =2.39-2.42,O-H-.. C1=3.14-3.24:~.
Keywords
Monoclinic crystal systemCrystallographyGadoliniumCrystal structureMoleculeChemistryBond lengthGroup (periodic table)Hydrogen bondX-ray crystallographyDiffractionPhysics
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Publication Info
- Year
- 1961
- Type
- article
- Volume
- 14
- Issue
- 3
- Pages
- 234-236
- Citations
- 116
- Access
- Closed
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Cite This
M. Marezio,
H. A. Plettinger,
W. H. Zachariasen
(1961).
The crystal structure of gadolinium trichloride hexahydrate.
Acta Crystallographica
, 14
(3)
, 234-236.
https://doi.org/10.1107/s0365110x61000796
Identifiers
- DOI
- 10.1107/s0365110x61000796