Abstract
Living polymerization techniques can be used to achieve a high degree of control over polymer chain architecture. Examples of the type of polymers that can be synthesized include block copolymers, comb-shaped polymers, multiarmed polymers, ladder polymers, and cyclic polymers. This control of structure, in turn, results in polymers with widely diverse physical properties, even though they are made from readily available low-cost monomers.
Keywords
Affiliated Institutions
Related Publications
Principles of Polymerization
Preface. 1. Introduction. 1.1 Types of Polymers and Polymerizations. 1.2 Nomenclature of Polymers. 1.3 Linear, Branched, and Crosslinked Polymers. 1.4 Molecular Weight. 1.5 Phys...
Living Radical Polymerization of Para-Substituted Styrenes and Synthesis of Styrene-Based Copolymers with Rhenium and Iron Complex Catalysts
Living radical polymerizations of para-substituted styrenes (p-chloro, p-methyl, p-acetoxy, p-acetoxymethyl) were examined with the oxo-complex of rhenium(V) [ReO2I: ReO2I(PPh3)...
Synthetic Polypeptide Mimics of Marine Adhesives
Water soluble copolypeptides containing l-dihydroxyphenylalanine (DOPA) and l-lysine were prepared by ring-opening polymerization of alpha-amino acid N-carboxyanhydride (NCA) mo...
Atom Transfer Radical Polymerization and the Synthesis of Polymeric Materials
The development of new controlled radical polymerization methods has progressed rapidly over the last five years. One of the most useful of these methods, atom transfer radical ...
Polymerization of Substituted Styrenes by Atom Transfer Radical Polymerization
A series of substituted styrenes were polymerized by controlled/"living" radical polymerization using atom transfer radical polymerization (ATRP), in order to correlate monomer ...
Publication Info
- Year
- 1991
- Type
- article
- Volume
- 251
- Issue
- 4996
- Pages
- 887-893
- Citations
- 760
- Access
- Closed
External Links
Social Impact
Social media, news, blog, policy document mentions
Citation Metrics
Cite This
Identifiers
- DOI
- 10.1126/science.251.4996.887