Abstract

The development of new controlled radical polymerization methods has progressed rapidly over the last five years. One of the most useful of these methods, atom transfer radical polymerization (ATRP), a powerful technique for the design and synthesis of new polymeric materials with novel structures, is reviewed. The Figure represents a hyperbranched polymer resulting from ATRP of p-chloromethylstyrene.

Keywords

Atom-transfer radical-polymerizationMaterials sciencePolymerizationLiving free-radical polymerizationRadical polymerizationReversible addition−fragmentation chain-transfer polymerizationPolymerPolymer chemistryCobalt-mediated radical polymerizationPolymer scienceComposite material

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Publication Info

Year
1998
Type
article
Volume
10
Issue
12
Pages
901-915
Citations
863
Access
Closed

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Timothy E. Patten, Krzysztof Matyjaszewski (1998). Atom Transfer Radical Polymerization and the Synthesis of Polymeric Materials. Advanced Materials , 10 (12) , 901-915. https://doi.org/10.1002/(sici)1521-4095(199808)10:12<901::aid-adma901>3.0.co;2-b

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DOI
10.1002/(sici)1521-4095(199808)10:12<901::aid-adma901>3.0.co;2-b