Abstract
Recent progress in sigma-chelation directed C-H functionalization from the authors' group is described to illustrate the challenges and opportunities in the development of synthetically-useful catalytic reactions involving C-H activation as the key step. Emphasis is placed on strategies for developing catalysis under mild conditions and controlling regio- and stereoselectivity.
Keywords
ChemistryStereoselectivityRegioselectivityCatalysisChelationCombinatorial chemistrySurface modificationOrganic chemistryStereochemistry
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Publication Info
- Year
- 2006
- Type
- review
- Volume
- 4
- Issue
- 22
- Pages
- 4041-4047
- Citations
- 303
- Access
- Closed
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Cite This
Jin‐Quan Yu,
Ramesh Giri,
Xiaohong Chen
(2006).
σ-Chelation-directed C–H functionalizations using Pd(<scp>ii</scp>) and Cu(<scp>ii</scp>) catalysts: regioselectivity, stereoselectivity and catalytic turnover.
Organic & Biomolecular Chemistry
, 4
(22)
, 4041-4047.
https://doi.org/10.1039/b611094k
Identifiers
- DOI
- 10.1039/b611094k