Abstract

We have carried out computer simulations to identify and characterize various thermally activated atomic scale processes that can play an important role in room temperature experiments where a metal tip is brought close to a metal surface. We find that contact formation between the tip and the surface can occur by a sequence of atomic hop and exchange processes which become active on a millisecond time scale when the tip is about 3--5 \AA{} from the surface. Adatoms on the surface are stabilized by the presence of the tip and energy barriers for diffusion processes in the region under the tip are reduced. This can cause adatoms to follow the tip as it is moved over the surface.

Keywords

Chemical physicsMaterials scienceMillisecondSurface diffusionAtomic unitsDiffusionMetalThermalSurface (topology)NanotechnologyMolecular physicsAtomic physicsPhysical chemistryChemistryAdsorptionThermodynamicsPhysics

Affiliated Institutions

Related Publications

Surface-enhanced Raman scattering

On the basis of different types of experiments, the authors develop implicitly the model of surface-enhanced Raman scattering (SERS) of adsorbates on metal surfaces. The long-ra...

1992 Journal of Physics Condensed Matter 1423 citations

Publication Info

Year
1996
Type
article
Volume
77
Issue
25
Pages
5067-5070
Citations
87
Access
Closed

Social Impact

Social media, news, blog, policy document mentions

Citation Metrics

87
OpenAlex
0
Influential
77
CrossRef

Cite This

Mads R. Sørensen, Karsten W. Jacobsen, Hannes Jónsson (1996). Thermal Diffusion Processes in Metal-Tip-Surface Interactions: Contact Formation and Adatom Mobility. Physical Review Letters , 77 (25) , 5067-5070. https://doi.org/10.1103/physrevlett.77.5067

Identifiers

DOI
10.1103/physrevlett.77.5067
PMID
10062706

Data Quality

Data completeness: 81%