Abstract
By means of a density functional approach, the phase equilibria of a fluid confined between two adsorbing walls, i.e., in a slitlike capillary, have been investigated. The theory provides a microscopic basis for the phenomenon of capillary condensation and, for fluids in narrow slits, predicts a line of critical points marking the end of the lines of coexistence between "liquid" and "gas" phases.
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Publication Info
- Year
- 1984
- Type
- article
- Volume
- 52
- Issue
- 7
- Pages
- 557-560
- Citations
- 169
- Access
- Closed
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Identifiers
- DOI
- 10.1103/physrevlett.52.557