Abstract

By means of a density functional approach, the phase equilibria of a fluid confined between two adsorbing walls, i.e., in a slitlike capillary, have been investigated. The theory provides a microscopic basis for the phenomenon of capillary condensation and, for fluids in narrow slits, predicts a line of critical points marking the end of the lines of coexistence between "liquid" and "gas" phases.

Keywords

Capillary condensationCondensationCapillary actionMaterials scienceLine (geometry)ThermodynamicsMechanicsPhysicsChemistryAdsorptionPhysical chemistry

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Publication Info

Year
1984
Type
article
Volume
52
Issue
7
Pages
557-560
Citations
169
Access
Closed

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Robert Evans, P. Tarazona (1984). Theory of Condensation in Narrow Capillaries. Physical Review Letters , 52 (7) , 557-560. https://doi.org/10.1103/physrevlett.52.557

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DOI
10.1103/physrevlett.52.557