The Topochemical 1,6-Polymerization of a Triene

Tram H. Hoang; Joseph W. Lauher; Frank W. Fowler

doi:10.1021/ja027444a

Abstract

The first topochemical 1,6-polymerization of a triene has been observed. The required supramolecular structure for this polymerization was achieved by the pi-pi stacking of the isonicotinate functionality. The crystal environment of this polymerization reaction controlled both the molecular and supramolecular structure of the polymer and allowed its structure to be determined by single-crystal X-ray diffraction.

Keywords

ChemistryPolymerizationSupramolecular chemistryStackingCrystal structurePolymerCrystallographyPolymer chemistryOrganic chemistry

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Publication Info

Year: 2002
Type: article
Volume: 124
Issue: 36
Pages: 10656-10657
Citations: 106
Access: Closed

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APA Style

                            
                                    Tram H. Hoang, 
                                
                                    Joseph W. Lauher, 
                                
                                    Frank W. Fowler
                                
                            (2002). 
                            The Topochemical 1,6-Polymerization of a Triene. 
                            Journal of the American Chemical Society
                            , 124
                            (36)
                            , 10656-10657.
                            https://doi.org/10.1021/ja027444a

Identifiers

DOI: 10.1021/ja027444a