Abstract

The electrodeposition of aluminum in the form of white or shiny adherent plates on various metals has been accomplished at room temperature. A satisfactory plating solution is prepared by mixing two moles of anhydrous aluminum chloride with 1 mole of ethyl pyridinium bromide, preferably in a dry, oxygen‐free atmosphere, to produce a liquid to which benzene (or toluene) is added until a second layer, principally excess benzene, forms on the top of the plating solution. Using an aluminum anode, plating may be carried out in a protected atmosphere at cathode current densities of approximately 1 amp/dm2 (about 9 amp/ft2) using voltages of the order of one volt.

Keywords

AnhydrousAnodeAluminiumBenzenePlating (geology)ChemistryBromideTolueneCathodeChloridePyridiniumInorganic chemistryHalideMaterials scienceElectrodeOrganic chemistry

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Publication Info

Year
1951
Type
article
Volume
98
Issue
5
Pages
207-207
Citations
266
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Frank H. Hurley, Thomas P. WIer (1951). The Electrodeposition of Aluminum from Nonaqueous Solutions at Room Temperature. Journal of The Electrochemical Society , 98 (5) , 207-207. https://doi.org/10.1149/1.2778133

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DOI
10.1149/1.2778133