Abstract
Abstract The title copper(I) compound has been isolated, whose X-ray crystallographic structure shows a rare polymerization mode in which the tetranuclear copper units, composed of three- and two-coordinate copper(I) atoms, are linked by pyrazines. This gives a cyclic voltammogram and a chrage transfer band characteristic of the polymeric structure in the solid state.
Keywords
ChemistryPyrazineCopperCrystallographyCrystal structureX-ray crystallographyChain (unit)StereochemistryDiffractionOrganic chemistryPhysicsQuantum mechanics
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Publication Info
- Year
- 1991
- Type
- article
- Volume
- 20
- Issue
- 4
- Pages
- 623-626
- Citations
- 15
- Access
- Closed
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Cite This
Susumu Kitagawa,
Megumu Munakata,
Tadashi Tanimura
(1991).
Tetranuclear Copper(I)-Based Infinite One-Dimentional Chain Complex. Synthesis and X-Ray Crystal Structure of {[Cu2(μ-3-methylpyridazine)2(μ-pyrazine)3](ClO4)2}∞.
Chemistry Letters
, 20
(4)
, 623-626.
https://doi.org/10.1246/cl.1991.623
Identifiers
- DOI
- 10.1246/cl.1991.623