Abstract

A pillared framework formed from 4,4'-bipyridine (bipy) and sheets of dinuclear Cd(2) nodes and 1,4-benzenedicarboxylic acid (bdc) linkers can be prepared in both interpenetrated and noninterpenetrated forms by simply varying the temperature or concentration of the reaction. These results demonstrate that higher temperatures and concentrations favor interpenetration over the corresponding noninterpenetrating structure, an observation that could have broad implications for controlling the synthesis of metal-organic materials.

Keywords

ChemistryMetalMetal-organic frameworkChemical engineeringBipyridineInorganic chemistryPolymer chemistryOrganic chemistryCrystal structure

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Year
2009
Type
article
Volume
131
Issue
47
Pages
17040-17041
Citations
380
Access
Closed

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Jianjun Zhang, Łukasz Wojtas, Randy W. Larsen et al. (2009). Temperature and Concentration Control over Interpenetration in a Metal−Organic Material. Journal of the American Chemical Society , 131 (47) , 17040-17041. https://doi.org/10.1021/ja906911q

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DOI
10.1021/ja906911q