Abstract

We use extended Mie theory to investigate optical forces induced by and acting on small silver nanoparticle aggregates excited at surface plasmon resonance. It is shown that single molecules can be trapped at junctions between closely spaced nanoparticles, which are simultaneously pulled together by optical forces. These effects could significantly influence surface-enhanced Raman scattering and related spectroscopies under normal experimental conditions and contribute to single-molecule sensitivity.

Keywords

Surface plasmon resonanceRaman scatteringMaterials scienceOptical forceMie scatteringSurface plasmonExcited statePlasmonLocalized surface plasmonNanoparticleScatteringMoleculeSilver nanoparticleMolecular physicsRaman spectroscopyResonance (particle physics)Light scatteringNanotechnologyChemical physicsOpticsOptoelectronicsOptical tweezersAtomic physicsChemistryPhysics

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Publication Info

Year
2002
Type
article
Volume
89
Issue
24
Pages
246802-246802
Citations
501
Access
Closed

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Cite This

Hongxing Xu, Mikael Käll (2002). Surface-Plasmon-Enhanced Optical Forces in Silver Nanoaggregates. Physical Review Letters , 89 (24) , 246802-246802. https://doi.org/10.1103/physrevlett.89.246802

Identifiers

DOI
10.1103/physrevlett.89.246802