Abstract

We report on measurements of the stiffness and breaking strength of monolayer MoS(2), a new semiconducting analogue of graphene. Single and bilayer MoS(2) is exfoliated from bulk and transferred to a substrate containing an array of microfabricated circular holes. The resulting suspended, free-standing membranes are deformed and eventually broken using an atomic force microscope. We find that the in-plane stiffness of monolayer MoS(2) is 180 ± 60 Nm(-1), corresponding to an effective Young's modulus of 270 ± 100 GPa, which is comparable to that of steel. Breaking occurs at an effective strain between 6 and 11% with the average breaking strength of 15 ± 3 Nm(-1) (23 GPa). The strength of strongest monolayer membranes is 11% of its Young's modulus, corresponding to the upper theoretical limit which indicates that the material can be highly crystalline and almost defect-free. Our results show that monolayer MoS(2) could be suitable for a variety of applications such as reinforcing elements in composites and for fabrication of flexible electronic devices.

Keywords

MonolayerMaterials scienceModulusBilayerStiffnessComposite materialSubstrate (aquarium)FabricationGrapheneMembraneBreaking strengthNanotechnologyElastic modulusChemistry

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Publication Info

Year
2011
Type
article
Volume
5
Issue
12
Pages
9703-9709
Citations
2512
Access
Closed

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Simone Bertolazzi, Jacopo Brivio, András Kis (2011). Stretching and Breaking of Ultrathin MoS<sub>2</sub>. ACS Nano , 5 (12) , 9703-9709. https://doi.org/10.1021/nn203879f

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DOI
10.1021/nn203879f