Abstract

The factors of the atomic size difference Delta and the enthalpy of mixing ΔHmix of the multi-component alloys were summarized from the literatures. The formation zones of solid-solution phases, intermediate phases, and bulk metallic glasses were determined and the validity was verified by experimental results. For forming the solid solution, the alloys should have high entropy of mixing, lower Delta, and not too negative and positive enthalpy of mixing.

Keywords

Solid solutionEnthalpy of mixingMaterials scienceEnthalpyEntropy of mixingThermodynamicsMixing (physics)Standard enthalpy change of formationHigh entropy alloysComponent (thermodynamics)Phase (matter)MetalMetallurgyMicrostructureChemistryPhysics

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Publication Info

Year
2008
Type
article
Volume
10
Issue
6
Pages
534-538
Citations
3082
Access
Closed

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Yong Zhang, Yuefei Zhou, Jianwei Lin et al. (2008). Solid‐Solution Phase Formation Rules for Multi‐component Alloys. Advanced Engineering Materials , 10 (6) , 534-538. https://doi.org/10.1002/adem.200700240

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DOI
10.1002/adem.200700240