Abstract

Photodiodes fabricated from conjugated polymers exhibit excellent sensitivity to visible-UV radiation. The photosensitivity increases with reverse bias voltage. The photoresponse of diodes fabricated from poly(3-octyl thiophene) is relatively flat in the visible and near UV; for wavelengths shorter than 550 nm, the absolute sensitivity is greater than 0.3 A/W under reverse bias of 15 V, larger than that of commercial UV-enhanced Si photodiodes. Photodiodes made from poly[2-methoxy-5-(2′-ethyl-hexyloxy)-1,4-phenylene vinylene], MEH-PPV, sensitized with C60, show similar sensitivity. The ease of fabrication into large size, arbitrary shapes, and even onto flexible substrates makes the polymer photodiode a novel photodetector with potential for use in a wide range of applications.

Keywords

PhotodiodeMaterials scienceOptoelectronicsPhotodetectorUltravioletDiodePhotosensitivityPolymerLight-emitting diodeVisible spectrumOptics

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Publication Info

Year
1994
Type
article
Volume
64
Issue
25
Pages
3422-3424
Citations
313
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Closed

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Gang Yu, K. Pakbaz, Alan J. Heeger (1994). Semiconducting polymer diodes: Large size, low cost photodetectors with excellent visible-ultraviolet sensitivity. Applied Physics Letters , 64 (25) , 3422-3424. https://doi.org/10.1063/1.111260

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DOI
10.1063/1.111260