Abstract
ABSTRACT Self-consistent fields without exchange have been calculated for the ground state of Pr 3+ and Tm 3+ . The spin-orbit coupling constant ζ(4 f ) is found to have the values 785 and 2742 cm −1 in Pr 3+ and Tm 3+ , respectively. The corresponding values of are 29·4 and 77·5 Å −3 . Values of the Slater integrals F 2 (4f, 4f), F 4 (4f, 4f) and F 6 (4f, 4f) are also given for each structure.
Keywords
Coupling constantAtomic physicsPhysicsGround stateState (computer science)Spin–orbit interactionChemistryNuclear physicsMathematicsQuantum mechanics
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Publication Info
- Year
- 1960
- Type
- article
- Volume
- 56
- Issue
- 1
- Pages
- 41-54
- Citations
- 50
- Access
- Closed
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Cite This
E. C. Ridley
(1960).
Self-consistent fields without exchange for Pr<sup>3+</sup> and Tm<sup>3+</sup>.
Mathematical Proceedings of the Cambridge Philosophical Society
, 56
(1)
, 41-54.
https://doi.org/10.1017/s0305004100034277
Identifiers
- DOI
- 10.1017/s0305004100034277