Abstract
PbI2 crystals have been intercalated with ammonia, methylamine (CH3NH2), ethylamine (C2H5NH2), and butylamine (C4H9NH2) for the first time. Raman spectra of these materials, and also of PbI2 intercalated with nonylamine (C9H19NH2) were obtained using an excitation wavelength of 514.531 nm. For comparison a study of the interaction of CdI2 with the same molecules is included. Raman spectroscopy in the range 10-500 cm-1 demonstrated the occurrence of a polytypic phase transition from 1 T to 3 T on intercalation of PbI2 and also that intercalation results in the breaking up of the crystal into many small crystallites. The existence of strong Pb-N interactions was demonstrated by both infrared and Raman spectroscopy.
Keywords
Raman spectroscopyEthylamineIntercalation (chemistry)MethylamineInfrared spectroscopySpectroscopyChemistryInfraredIodideMoleculeAnalytical Chemistry (journal)Materials scienceCrystallographyInorganic chemistryPhysical chemistryOpticsOrganic chemistry
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Publication Info
- Year
- 1993
- Type
- article
- Volume
- 5
- Issue
- 35
- Pages
- 6407-6418
- Citations
- 55
- Access
- Closed
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Cite This
Rachel Warren,
Wenyao Liang
(1993).
Raman spectroscopy of new lead iodide intercalation compounds.
Journal of Physics Condensed Matter
, 5
(35)
, 6407-6418.
https://doi.org/10.1088/0953-8984/5/35/006
Identifiers
- DOI
- 10.1088/0953-8984/5/35/006