One-Step Synthesis and Structure of an Oligo(spiro-orthocarbonate)

Abstract

The reaction of pentaerythritol and tetraethylorthocarbonate at 260 degrees C for 12 h yields a white crystalline material that was characterized by 13C CPMAS NMR, CHN analysis, FT-IR, electron and X-ray powder diffraction, and Rietveld analysis. The white crystalline material was found to have the formula C6H8O4 and a crystal structure with a monoclinic cell [a = 9.167 A, b = 5.681 A, c = 5.880 A, beta = 90.0 degrees , space group I2] of hexagonally arranged spiro-oligomeric chains.

Keywords

ChemistryCombinatorial chemistryStereochemistry

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Publication Info

Year: 2002
Type: article
Volume: 124
Issue: 18
Pages: 4942-4943
Citations: 19
Access: Closed

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APA Style

                            
                                
                                    D. Vodak, 
                                
                                    Matthew Braun, 
                                
                                    Lykourgos Iordanidis
                                
                                et al.
                            
                            (2002). 
                            One-Step Synthesis and Structure of an Oligo(spiro-orthocarbonate). 
                            Journal of the American Chemical Society
                            , 124
                            (18)
                            , 4942-4943.
                            https://doi.org/10.1021/ja017683i
                        

Identifiers

DOI: 10.1021/ja017683i