Abstract

It is shown that, under certain conditions, measurements on the emission and absorption of luminescent centers allow the determination of the configurational coordinate curves for the ground and excited states of the centers. The method is used as a first approximation in obtaining configurational coordinate curves for divalent manganese in zinc silicate. These curves offer an explanation of the asymmetry of the manganese emission. Comparison of the energy levels for the manganese ion in the solid and gaseous state leads to an identification of the various levels and to the suggestion that emission in the solid state corresponds to a 4G→6S transition.

Keywords

ManganeseLuminescenceDivalentExcited stateMaterials scienceAbsorption (acoustics)SilicateChemistryAtomic physicsPhotochemistryInorganic chemistryAnalytical Chemistry (journal)Chemical physicsPhysicsOptoelectronics

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Publication Info

Year
1952
Type
article
Volume
42
Issue
12
Pages
910-910
Citations
91
Access
Closed

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Clifford C. Klick, James H. Schulman (1952). On the Luminescence of Divalent Manganese in Solids. Journal of the Optical Society of America , 42 (12) , 910-910. https://doi.org/10.1364/josa.42.000910

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DOI
10.1364/josa.42.000910