Many-Body Perturbation Theory and Coupled Cluster Theory for Electron Correlation in Molecules

1981 Annual Review of Physical Chemistry 2,087 citations

Abstract

Ten years ago in the Annual Review of Physical Chemistry. there was a review article entitled Many-Body Theories of the Electronic Structure of Atoms and Molecules, by Karl Freed ( 1 ) . In that article many-body methods were defined to be those techniques which derive their impetus from theories of the N-body problem for which N --+ 00. For the purposes of this review, we further specify these methods as many-body perturba­ tion theory (MBPT) (2-5) and the closely related coupled-cluster meth­ ods (CCM) (6-9) . In the ten years since that review appeared, probably no area in theo­ retical chemistry has undergone more development than has the theory, methodology, and applications of such ab initio many-body methods for

Keywords

Coupled clusterElectronic correlationPerturbation theory (quantum mechanics)CorrelationStatistical physicsPhysicsCluster (spacecraft)ElectronPerturbation (astronomy)Many-body theoryAtomic physicsQuantum mechanicsMoleculeMathematicsComputer scienceGeometry

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Publication Info

Year
1981
Type
article
Volume
32
Issue
1
Pages
359-401
Citations
2087
Access
Closed

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Rodney J. Bartlett (1981). Many-Body Perturbation Theory and Coupled Cluster Theory for Electron Correlation in Molecules. Annual Review of Physical Chemistry , 32 (1) , 359-401. https://doi.org/10.1146/annurev.pc.32.100181.002043

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DOI
10.1146/annurev.pc.32.100181.002043