Abstract

Diamond may be grown at low pressures where it is the metastable form of carbon. Recent advances in a wide variety of plasma and electrical discharge methods have led to dramatic increases in growth rates. All of these methods have certain aspects in common, namely, the presence of atomic hydrogen and the production of energetic carbon-containing fragments under conditions that support high mobilities on the diamond surface. Some understanding of the processes taking place during nucleation and growth of diamond has been achieved, but detailed molecular mechanisms are not yet known. Related research has led to the discovery of a new class of materials, the "diamondlike" phases. Vapor-grown diamond and diamondlike materials may have eventual applications in abrasives, tool coatings, bearing surfaces, electronics, optics, tribological surfaces, and corrosion protection.

Keywords

DiamondNucleationMaterials scienceMetastabilityCarbon fibersNanotechnologyCarbon filmMaterial properties of diamondTribologyThin filmComposite numberMetallurgyComposite materialChemistry

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2008 Physical Review B 75 citations

Publication Info

Year
1988
Type
article
Volume
241
Issue
4868
Pages
913-921
Citations
1566
Access
Closed

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Cite This

John C. Angus, C. Hayman (1988). Low-Pressure, Metastable Growth of Diamond and "Diamondlike" Phases. Science , 241 (4868) , 913-921. https://doi.org/10.1126/science.241.4868.913

Identifiers

DOI
10.1126/science.241.4868.913