Abstract

Three novel coordination polymers, [Ag(N–N)2]X (N–N = 4,4′-bipyridyl, X = CF3SO3––1; N–N = 4-cyanopyridine, X = BF4–, in two polymorphs, 2 and 3)], are prepared and investigated by single crystal X-ray analysis; 1 and 2 contain three-dimensional cationic frameworks, both consisting of four equivalent interpenetrating diamondoid lattices, while 3 is formed by two-dimensional layers of distorted squares.

Keywords

DiamondoidCationic polymerizationDenticityChemistryCrystallographyRodPolymerSingle crystalStereochemistryCrystal structureMoleculePolymer chemistryOrganic chemistry

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Publication Info

Year
1994
Type
article
Issue
24
Pages
2755-2756
Citations
240
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Closed

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Lucia Carlucci, Gíanfranco Ciani, Davide Μ. Proserpio et al. (1994). Interpenetrating diamondoid frameworks of silver(<scp>I</scp>) cations linked by N,N′-bidentate molecular rods. Journal of the Chemical Society Chemical Communications (24) , 2755-2756. https://doi.org/10.1039/c39940002755

Identifiers

DOI
10.1039/c39940002755