Abstract
A [1,1,1,1]metacyclophane blocked in the 1,3-alternate conformation and bearing four pyridine units leads, under self-assembly conditions in the crystalline phase, to the formation of a fourfold interpenetrated 3-D co-ordination network in the presence of silver cations; the 3-D net is generated through the bridging by linearly co-ordinated silver cations of consecutive tectons presenting a pseudo-tetrahedral arrangement of four co-ordination sites.
Keywords
ChemistryOrdinationCrystallographyBridging (networking)TetrahedronPyridineCageStereochemistryOrganic chemistry
Affiliated Institutions
Related Publications
Novel gold‐dithiol nano‐networks with non‐metallic electronic properties
Stable nanostructured networks of quantum‐sized particles have been prepared “see Figure” using self‐assembly techniques. Here, two new techniques are reported for the preparati...
Supramolecular Chemistry
Part 1 From molecular to supramolecular chemistry: concepts and language of supramolecular chemistry. Part 2 Molecular recognition: recognition, information, complementarity mol...
Publication Info
- Year
- 2001
- Type
- article
- Volume
- 25
- Issue
- 2
- Pages
- 207-209
- Citations
- 53
- Access
- Closed
External Links
Social Impact
Altmetric
PlumX Metrics
Social media, news, blog, policy document mentions
Citation Metrics
53
OpenAlex
Cite This
Ce ́dric Klein,
Ernest Graf,
Mir Wais Hosseini
et al.
(2001).
Design and structural analysis of interpenetrated 3-D co-ordination networks formed by self-assembly using tetrapyridinocyclophane and silver cations.
New Journal of Chemistry
, 25
(2)
, 207-209.
https://doi.org/10.1039/b008259g
Identifiers
- DOI
- 10.1039/b008259g