Abstract
A simple method for the synthesis of a series of cross-linked poly(orthocarbonate)s (CPOC), based on tetraethyl orthocarbonate, is reported. Structural evidence for CPOCs was obtained from 13C solid-state NMR, FT-IR, and thermal analysis. All polymers have high and fast uptake of organic fluids such as tetrahydrofuran, dichloromethane, dichloroethane, and the dry-cleaning fluid blend "trichlor".
Keywords
DichloromethaneTetrahydrofuranSolventChemistryPolymerDichloroethane12-DichloroethaneSolid-statePolymer chemistryOrganic chemistryOrganic solventChemical engineeringPhysical chemistry
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Publication Info
- Year
- 2005
- Type
- article
- Volume
- 38
- Issue
- 5
- Pages
- 1623-1626
- Citations
- 99
- Access
- Closed
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Cite This
Hayal Bülbül Sönmez,
Fred Wudl
(2005).
Cross-Linked Poly(orthocarbonate)s as Organic Solvent Sorbents.
Macromolecules
, 38
(5)
, 1623-1626.
https://doi.org/10.1021/ma048731x
Identifiers
- DOI
- 10.1021/ma048731x