Abstract
Despite the extraordinary promise of single-wall carbon nanotubes, their realistic application in materials and devices has been hindered by processing and manipulation difficulties. Now that this unique material is readily available in near kilogram quantities (albeit still at high cost), research into means of chemical alteration is in full swing. The covalent attachment of appropriate moieties is anticipated to facilitate applications development by improving solubility and ease of dispersion, and providing for chemical attachment to surfaces and polymer matrices. While it is clear that more investigation is needed to elucidate the nature and locality of covalently attached moieties, developments to date indicate that carbon nanotubes may indeed be considered a true segment of organic chemistry. In this contribution, we review the current state of carbon nanotube covalent chemistry, and convey our anxious expectation that further developments will follow.
Keywords
Affiliated Institutions
Related Publications
Recent Advances in the Preparation and Utilization of Carbon Nanotubes for Hydrogen Storage
Recent progress in the production, purification, and experimental and theoretical investigations of carbon nanotubes for hydrogen storage are reviewed. From the industrial point...
UNUSUAL PROPERTIES AND STRUCTURE OF CARBON NANOTUBES
▪ Abstract The unusual structure and properties of carbon nanotubes are presented, with particular reference to single-wall nanotubes (SWNTs) and nanotube properties that differ...
Elastic strain of freely suspended single-wall carbon nanotube ropes
We have induced large elastic strains in ropes of single-wall carbon nanotubes, using an atomic force microscope in lateral force mode. Freely suspended ropes were observed to d...
Simulations of Nanocylinders Self-Assembled from Cyclic β-Tripeptides
This paper examines the self-assembly of cyclic β-tripeptides using density functional theory. On the basis of literature precedents, these cyclic peptides were expected to self...
Molecular Scale Buckling Mechanics in Individual Aligned Single-Wall Carbon Nanotubes on Elastomeric Substrates
We have studied the scaling of controlled nonlinear buckling processes in materials with dimensions in the molecular range (i.e., approximately 1 nm) through experimental and th...
Publication Info
- Year
- 2002
- Type
- article
- Volume
- 12
- Issue
- 7
- Pages
- 1952-1958
- Citations
- 858
- Access
- Closed
External Links
Social Impact
Social media, news, blog, policy document mentions
Citation Metrics
Cite This
Identifiers
- DOI
- 10.1039/b201013p