Abstract

From an isothermal molecular-dynamics experiment of an unstable two-dimensional fluid undergoing phase separation, two principal growth regimes are observed: (1) spinodal decomposition with a wavelike morphology followed by (2) a transition to cluster formation and growth due to atomic condensation and cluster coagulation. The time-dependent power-law behavior for the second growth regime is 0.5, in contrast to a constant-energy simulation which yields a power-law behavior of 0.33. Details of the phase-separation dynamics are discussed and compared with theory.

Keywords

Spinodal decompositionScalingMolecular dynamicsCluster (spacecraft)CondensationPower lawIsothermal processStatistical physicsConstant (computer programming)Dynamics (music)Materials sciencePhase (matter)PhysicsThermodynamics

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Year
1982
Type
article
Volume
49
Issue
13
Pages
923-926
Citations
68
Access
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Farid F. Abraham, S. W. Koch, Rashmi C. Desai (1982). Computer-Simulation Dynamics of an Unstable Two-Dimensional Fluid: Time-Dependent Morphology and Scaling. Physical Review Letters , 49 (13) , 923-926. https://doi.org/10.1103/physrevlett.49.923

Identifiers

DOI
10.1103/physrevlett.49.923