[Co5(im)10⋅2 MB]∞: A Metal-Organic Open-Framework with Zeolite-Like Topology

Abstract

A highly robust metal-organic zeotype was created by expansion of the zeolite topology. The novel nanoporous material [Co5(im)10⋅2 MB]∞ (see structure) exhibits not only a zeolite-like topology, but also the chemically functionalizable properties of zeolites; im=imidazole, MB=3-methyl-1-butanol.

Keywords

ZeoliteNanoporousMicroporous materialTopology (electrical circuits)Metal-organic frameworkMetalImidazoleMaterials scienceChemistryOrganic chemistryNanotechnologyCatalysisAdsorption

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Publication Info

Year: 2002
Type: article
Volume: 41
Issue: 8
Pages: 1384-1386
Citations: 245
Access: Closed

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APA Style

                            
                                
                                    Yun‐Qi Tian, 
                                
                                    Chenxin Cai, 
                                
                                    Yong Ji
                                
                                et al.
                            
                            (2002). 
                            [Co5(im)10⋅2 MB]∞: A Metal-Organic Open-Framework with Zeolite-Like Topology. 
                            Angewandte Chemie International Edition
                            , 41
                            (8)
                            , 1384-1386.
                            https://doi.org/10.1002/1521-3773(20020415)41:8<1384::aid-anie1384>3.0.co;2-6
                        

Identifiers

DOI: 10.1002/1521-3773(20020415)41:8<1384::aid-anie1384>3.0.co;2-6

[Co5(im)10⋅2 MB]∞: A Metal-Organic Open-Framework with Zeolite-Like Topology

Abstract

Keywords

Affiliated Institutions

Related Publications

Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks

Functional Micropore Chemistry of Crystalline Metal Complex-Assembled Compounds

A Chemically Functionalizable Nanoporous Material [Cu <sub>3</sub> (TMA) <sub>2</sub> (H <sub>2</sub> O) <sub>3</sub> ] <sub> <i>n</i> </sub>

Size-Selective Lewis Acid Catalysis in a Microporous Metal-Organic Framework with Exposed Mn<sup>2+</sup> Coordination Sites

Zeolite-like crystal structure of an empty microporous molecular framework

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Social Impact

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