Abstract

Direct water electrolysis was achieved with a novel, integrated, monolithic photoelectrochemical-photovoltaic design. This photoelectrochemical cell, which is voltage biased with an integrated photovoltaic device, splits water directly upon illumination; light is the only energy input. The hydrogen production efficiency of this system, based on the short-circuit current and the lower heating value of hydrogen, is 12.4 percent.

Keywords

Photovoltaic systemHydrogen productionWater splittingPhotoelectrochemical cellElectrolysis of waterHydrogenOptoelectronicsMaterials sciencePhotoelectrolysisElectrolysisVoltageElectrical engineeringChemistryElectrodePhotocatalysisEngineeringCatalysis

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Publication Info

Year
1998
Type
article
Volume
280
Issue
5362
Pages
425-427
Citations
2163
Access
Closed

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O. Khaselev, John A. Turner (1998). A Monolithic Photovoltaic-Photoelectrochemical Device for Hydrogen Production via Water Splitting. Science , 280 (5362) , 425-427. https://doi.org/10.1126/science.280.5362.425

Identifiers

DOI
10.1126/science.280.5362.425