Abstract

A luminescent mixed lanthanide metal-organic framework approach has been realized to explore luminescent thermometers. The targeted self-referencing luminescent thermometer Eu(0.0069)Tb(0.9931)-DMBDC (DMBDC = 2, 5-dimethoxy-1, 4-benzenedicarboxylate) based on two emissions of Tb(3+) at 545 nm and Eu(3+) at 613 nm is not only more robust, reliable, and instantaneous but also has higher sensitivity than the parent MOF Tb-DMBDC based on one emission at a wide range from 10 to 300 K.

Keywords

LanthanideThermometerLuminescenceChemistryMetal-organic frameworkLuminescent MeasurementsMetalNanotechnologyInorganic chemistryPhotochemistryAnalytical Chemistry (journal)Physical chemistryOptoelectronicsOrganic chemistryThermodynamicsIonMaterials science

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Publication Info

Year
2012
Type
article
Volume
134
Issue
9
Pages
3979-3982
Citations
1128
Access
Closed

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Yuanjing Cui, Hui Xu, Yan‐Feng Yue et al. (2012). A Luminescent Mixed-Lanthanide Metal–Organic Framework Thermometer. Journal of the American Chemical Society , 134 (9) , 3979-3982. https://doi.org/10.1021/ja2108036

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DOI
10.1021/ja2108036