Abstract

We present a simple and intuitive picture, an electromagnetic analog of molecular orbital theory, that describes the plasmon response of complex nanostructures of arbitrary shape. Our model can be understood as the interaction or “hybridization” of elementary plasmons supported by nanostructures of elementary geometries. As an example, the approach is applied to the important case of a four-layer concentric nanoshell, where the hybridization of the plasmons of the inner and outer nanoshells determines the resonant frequencies of the multilayer nanostructure.

Keywords

NanoshellPlasmonNanostructureSurface plasmonPhysicsConcentricSurface plasmon resonanceNanotechnologyMaterials scienceOptoelectronicsNanoparticleGeometryMathematics

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Publication Info

Year
2003
Type
article
Volume
302
Issue
5644
Pages
419-422
Citations
3882
Access
Closed

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Emil Prodan, Corey Radloff, Naomi J. Halas et al. (2003). A Hybridization Model for the Plasmon Response of Complex Nanostructures. Science , 302 (5644) , 419-422. https://doi.org/10.1126/science.1089171

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DOI
10.1126/science.1089171